Astronomers discover new exoplanet similar in size to Earth; Planet Kepler-21b found using space and ground-based observations

ScienceDaily (Nov. 30, 2011) — The NASA Kepler Mission is designed to survey a portion of our region of the Milky Way Galaxy to discover Earth-size planets in or near the "habitable zone," the region in a planetary system where liquid water can exist, and determine how many of the billions of stars in our galaxy have such planets. It now has another planet to add to its growing list.

A research team led by Steve Howell, of NASA's Ames Research Center, has shown that one of the brightest stars in the Kepler star field has a planet with a radius only 1.6 that of Earth's radius and a mass no greater that 10 Earth masses, circling its parent star with a 2.8-day period. With such a short period, and such a bright star, the team of over 65 astronomers -- which included David Silva, Ken Mighell and Mark Everett of the National Optical Astronomy Observatory (NOAO) -- needed multiple telescopes on the ground to support and confirm their Kepler observations. These included the 4-meter Mayall telescope and the WIYN telescope at Kitt Peak National Observatory.

With a period of only 2.8 days, this planet, designated Kepler-21b, is only about 6 million kilometers away from its parent star. By comparison Mercury, the closest planet to the sun, has a period of 88 days and a distance from the sun almost ten times greater, or 57 million km. So Kepler 21b is far hotter than any place humans could venture. The team calculates that the temperature at the surface of the planet is about 1900 K, or 2960 F. While this temperature is nowhere near the habitable zone in which liquid water might be found, the planet's size is approaching that of Earth.

The parent star, HD 179070, is quite similar to our sun: its mass is 1.3 solar masses, its radius is 1.9 solar radii, and its age, based on stellar models, is 2.84 billion years (or a bit younger than the sun's 4.6 billion years). HD 179070 is spectral type F6 IV, a little hotter and brighter than the sun. By astronomical standards, HD 179070 is fairly close, at a distance from the sun of 352 light years. While it cannot be seen by the unaided eye, a small telescope can easily pick it out.

Part of the difficulty in detecting this planet is the realization, from the Kepler mission, that many stars show short period brightness oscillations. The effect of these must be removed from the stellar light in order to uncover the regular, but very small, dimming caused by the planet passing in front of the star. The Kepler mission observed this field for over 15 months, and the team combined the observations to enable them to detect this tiny, periodic signal. They also relied on spectroscopic and imaging data from a number of ground based telescopes.

The results of this work have been accepted for publication in the Astrophysical Journal.

NOAO is operated by Association of Universities for Research in Astronomy Inc. (AURA) under a cooperative agreement with the National Science Foundation.

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The above story is reprinted from materials provided by National Optical Astronomy Observatory.

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Highly efficient oxygen catalyst found: Rechargeable batteries and hydrogen-fuel production could benefit

ScienceDaily (Oct. 28, 2011) — A team of researchers at MIT has found one of the most effective catalysts ever discovered for splitting oxygen atoms from water molecules -- a key reaction for advanced energy-storage systems, including electrolyzers, to produce hydrogen fuel and rechargeable batteries. This new catalyst liberates oxygen at more than 10 times the rate of the best previously known catalyst of its type.

The new compound, composed of cobalt, iron and oxygen with other metals, splits oxygen from water (called the Oxygen Evolution Reaction, or OER) at a rate at least an order of magnitude higher than the compound currently considered the gold standard for such reactions, the team says. The compound's high level of activity was predicted from a systematic experimental study that looked at the catalytic activity of 10 known compounds.

The team, which includes materials science and engineering graduate student Jin Suntivich, mechanical engineering graduate student Kevin J. May and professor Yang Shao-Horn, published their results in Science on Oct. 28.

The scientists found that reactivity depended on a specific characteristic: the configuration of the outermost electron of transition metal ions. They were able to use this information to predict the high reactivity of the new compound -- which they then confirmed in lab tests.

"We not only identified a fundamental principle" that governs the OER activity of different compounds, "but also we actually found this new compound" based on that principle, says Shao-Horn, the Gail E. Kendall (1978) Associate Professor of Mechanical Engineering and Materials Science and Engineering.

Many other groups have been searching for more efficient catalysts to speed the splitting of water into hydrogen and oxygen. This reaction is key to the production of hydrogen as a fuel to be used in cars; the operation of some rechargeable batteries, including zinc-air batteries; and to generate electricity in devices called fuel cells. Two catalysts are needed for such a reaction -- one that liberates the hydrogen atoms, and another for the oxygen atoms -- but the oxygen reaction has been the limiting factor in such systems.

Other groups, including one led by MIT's Daniel Nocera, have focused on similar catalysts that can operate -- in a so-called "artificial leaf" -- at low cost in ordinary water. But such reactions can occur with higher efficiency in alkaline solutions, which are required for the best previously known catalyst, iridium oxide, as well as for this new compound.

Shao-Horn and her collaborators are now working with Nocera, integrating their catalyst with his artificial leaf to produce a self-contained system to generate hydrogen and oxygen when placed in an alkaline solution. They will also be exploring different configurations of the catalyst material to better understand the mechanisms involved. Their initial tests used a powder form of the catalyst; now they plan to try thin films to better understand the reactions.

In addition, even though they have already found the highest rate of activity yet seen, they plan to continue searching for even more efficient catalyst materials. "It's our belief that there may be others with even higher activity," Shao-Horn says.

Jens Norskov, a professor of chemical engineering at Stanford University and director of the Suncat Center for Interface Science and Catalysis there, who was not involved in this work, says, "I find this an extremely interesting 'rational design' approach to finding new catalysts for a very important and demanding problem."

The research, which was done in collaboration with visiting professor Hubert A. Gasteiger (currently a professor at the Technische Universität München in Germany) and professor John B. Goodenough from the University of Texas at Austin, was supported by the U.S. Department of Energy's Hydrogen Initiative, the National Science Foundation, the Toyota Motor Corporation and the Chesonis Foundation.

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The above story is reprinted from materials provided by Massachusetts Institute of Technology. The original article was written by David L. Chandler, MIT News Office.

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Journal Reference:

J. Suntivich, K. J. May, H. A. Gasteiger, J. B. Goodenough, Y. Shao-Horn. A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles. Science, 2011; DOI: 10.1126/science.1212858

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